Sustainable Ultra-High-Performance Concrete: Incorporating Nano-Eggshell Waste for Improved Strength and Durability
Keywords:
Ultra-high-performance concrete, Nano-eggshell, Mechanical properties, SorptivityAbstract
This study examines the mechanical and microstructural properties of ultra-high-performance concrete (UHPC) incorporating nano-eggshell (NES) particles as a sustainable alternative to conventional nanofillers. Eggshell waste, consisting primarily of calcium carbonate, was processed through cleaning, calcination, and grinding to obtain nanosized particles. UHPC mixtures with varying NES contents (1-5%) were prepared and evaluated for compressive strength, splitting tensile strength, and sorptivity at different curing ages. The results indicate that the optimal NES dosage of 3% significantly enhanced the compressive strength of UHPC by 4.9%, 6.0%, and 4.5% at 7, 28, and 90 days, respectively, compared to the reference mixture. The splitting tensile strength at 28 days also improved by 16.9% with 3% NES. The sorptivity of UHPC was reduced by 28% at the optimal NES content, indicating its improved durability. XRD analysis revealed the presence of calcium carbonate and its interactions with the cementitious matrix. The performance improvements were attributed to the nanofiller effect, accelerated hydration, and microstructural refinement induced by NES particles. However, excessive NES addition beyond the optimal dosage led to slight reductions in the mechanical properties owing to agglomeration effects. The findings demonstrate the potential of nano-eggshell waste as a sustainable and performance-enhancing alternative in UHPC, contributing to the development of eco-friendly construction material.
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[1] S. Zhao, W. Sun, Nano-mechanical behavior of a green ultra-high performance concrete, Construction and Building Materials 63 (2014) 150-160.
[2] M. Heikal, H.A. Abdel-Gawwad, F.A. Ababneh, Positive impact performance of hybrid effect of nano-clay and silica nano-particles on composite cements, Construction and Building Materials 190 (2018) 508-516.
[3] Z. Wu, C. Shi, K.H. Khayat, L. Xie, Effect of SCM and nano-particles on static and dynamic mechanical properties of UHPC, Construction and Building Materials 182 (2018) 118-125.
[4] G. Xiaoyu, F. Yingfang, L. Haiyang, The compressive behavior of cement mortar with the addition of nano metakaolin, Nanomaterials and Nanotechnology 8 (2018) 184798041875559.
[5] G.F. Huseien, K.W. Shah, A.R.M. Sam, Sustainability of nanomaterials based self-healing concrete: An all-inclusive insight, Journal of Building Engineering 23 (2019) 155-171.
[6] P. Zhang, J. Wan, K. Wang, Q. Li, Influence of nano-SiO 2 on properties of fresh and hardened high performance concrete: A state-of-the-art review, Construction and Building Materials 148 (2017) 648-658.
[7] M. Eltaher, M. Khater, S. Park, E. Abdel-Rahman, M.J.A.i.n.r. Yavuz, On the static stability of nonlocal nanobeams using higher-order beam theories, 4(1) (2016) 51.
[8] S.A. Mostafa, A.S. Faried, A.A. Farghali, M.M. El-Deeb, T.A. Tawfik, S. Majer, M. Abd Elrahman, Influence of Nanoparticles from Waste Materials on Mechanical Properties, Durability and Microstructure of UHPC, Materials (Basel) 13(20) (2020).
[9] S.A. Mostafa, I.N. Fathy, A.A. Mahmoud, M.A. Abouelnour, K. Mahmoud, S.M. Shaaban, S.A. Elhameed, I.M.J.A.o.N.E. Nabil, Optimization of UHPC with basil plant ash: Impacts on strength, durability, and gamma-ray attenuation, 226 (2026) 111825.
[10] Z. Wang, X. Nie, J.-S. Fan, X.-Y. Lu, R. Ding, Experimental and numerical investigation of the interfacial properties of non-steam-cured UHPC-steel composite beams, Construction and Building Materials 195 (2019) 323-339.
[11] E. Ghafari, H. Costa, E. Júlio, Statistical mixture design approach for eco-efficient UHPC, Cement and Concrete Composites 55 (2015) 17-25.
[12] K. Liu, R. Yu, Z. Shui, X. Li, C. Guo, B. Yu, S. Wu, Optimization of autogenous shrinkage and microstructure for Ultra-High Performance Concrete (UHPC) based on appropriate application of porous pumice, Construction and Building Materials 214 (2019) 369-381.
[13] M. Ozawa, S. Subedi Parajuli, Y. Uchida, B. Zhou, Preventive effects of polypropylene and jute fibers on spalling of UHPC at high temperatures in combination with waste porous ceramic fine aggregate as an internal curing material, Construction and Building Materials 206 (2019) 219-225.
[14] Y. Zhang, Q. Zhang, A.H. AlAteah, A. Essam, S.A.J.C.S.i.C.M. Mostafa, Predictive modeling for mechanical characteristics of ultra high-performance concrete blended with eggshell powder and nano silica utilizing traditional technique and machine learning algorithm, 21 (2024) e04025.
[15] P. Murthi, V. Lavanya, K. Poongodi, Effect of eggshell powder on structural and durability properties of high strength green concrete for sustainability: A critical review, Materials Today: Proceedings (2022).
[16] R. Othman, B.W. Chong, R.P. Jaya, M.R. Mohd Hasan, M.M. Al Bakri Abdullah, M.H. Wan Ibrahim, Evaluation on the rheological and mechanical properties of concrete incorporating eggshell with tire powder, Journal of Materials Research and Technology 14 (2021) 439-451.
[17] Z. Quanwei, C. Qi, A.H. AlAteah, A.M. Alfares, S. Alinsaif, S.A.J.R.o.A.M.S. Mostafa, AI-based prediction for the strength, cost, and sustainability of eggshell and date palm ash-blended concrete, 64(1) (2025) 20250113.
[18] L.P. Singh, S.R. Karade, S.K. Bhattacharyya, M.M. Yousuf, S. Ahalawat, Beneficial role of nanosilica in cement based materials – A review, Construction and Building Materials 47 (2013) 1069-1077.
[19] H.K. Tchakouté, D.E. Tchinda Mabah, C. Henning Rüscher, E. Kamseu, F. Andreola, M.C. Bignozzi, C. Leonelli, Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements, Journal of Asian Ceramic Societies 8(1) (2020) 149-161.
[20] A.S. Aadi, N.H. Sor, A.A. Mohammed, The behavior of eco-friendly self – compacting concrete partially utilized ultra-fine eggshell powder waste, Journal of Physics: Conference Series 1973(1) (2021).
[21] Y. Zhu, H. Hussein, A. Kumar, G. Chen, A review: Material and structural properties of UHPC at elevated temperatures or fire conditions, Cement and Concrete Composites 123 (2021).
[22] J.L. García Calvo, G. Pérez, P. Carballosa, E. Erkizia, J.J. Gaitero, A. Guerrero, Development of ultra-high performance concretes with self-healing micro/nano-additions, Construction and Building Materials 138 (2017) 306-315.
[23] A.a.R. Al-Shamasneh, A. Mahmoodzadeh, M. Kewalramani, A. Alghamdi, J. Alnahas, M. Sulaiman, N. Ghazouani, I.J.S.R. Albaijan, Hybrid machine learning models for predicting the tensile strength of reinforced concrete incorporating nano-engineered and sustainable supplementary cementitious materials, 15(1) (2025) 35805.
[24] J. Xie, H. Zhang, L. Duan, Y. Yang, J. Yan, D. Shan, X. Liu, J. Pang, Y. Chen, X. Li, Y. Zhang,Effect of nano metakaolin on compressive strength of recycled concrete, Construction and Building Materials 256 (2020) 119393.
[25] A. Adesina, Durability Enhancement of Concrete Using Nanomaterials: An Overview, Materials Science Forum 967 (2019) 221-227.
[26] H. Du, S. Du, X. Liu, Durability performances of concrete with nano-silica, Construction and Building Materials 73 (2014) 705-712.
[27] H. Wu, J. Gao, C. Liu, Y. Zhao, S.J.J.o.B.E. Li, Development of nano-silica modification to enhance the micro-macro properties of cement-based materials with recycled clay brick powder, 86 (2024) 108854.
[28] W. Yonggui, L. Shuaipeng, P. Hughes, F. Yuhui, Mechanical properties and microstructure of basalt fibre and nano-silica reinforced recycled concrete after exposure to elevated temperatures, Construction and Building Materials 247 (2020) 118561.
[29] K. Nandhini, J. Karthikeyan, Sustainable and greener concrete production by utilizing waste eggshell powder as cementitious material – A review, Construction and Building Materials 335 (2022).
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